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Resource Book for Sixth-Form Practical Chemistry
Experiment 12
Green Chemistry: An Environmental-Friendly Preparation of 1,6-Hexanedioic Acid
A quick-fit drying tube packed with anhydrous calcium chloride | |
Sodium tungstate(VI) dihydrate (Na2WO4 · 2H2O) added into the round-bottomed flask | |
Adding aliquat 336 (the phase transfer catalyst) to the reaction mixture | |
Hydrogen peroxide (H2O2) added to the reaction mixture | |
Heating the reaction mixture under reflux with an hot oil bath | |
Cooling the reaction mixture to room temperature | |
Cooling the reaction mixture in an ice-water bath. White crystalline solid formed. | |
Collecting the crystalline 1,6-hexanedioic acid by suction filtration | |
The product – 1,6-hexanedioic acid |
2004 Department of Chemistry, The Chinese University of Hong Kong