The growth of high-quality tin-based perovskite films remains a grand challenge due to the uncontrollable crystallization kinetics. Here, we report a facile strategy to realize an epitaxial-like growth of highly oriented tin-based perovskite films with the assistance of perovskite quantum dots (PQDs). Synchrotron-based in situ X-ray scattering results reveal that PQDs can act as nucleation centers to promote the growth of highly oriented perovskite crystals for both FASnI₃ and MASnI₃ systems.… Read More

Designing new high-performance non-fullerene acceptors is the key driving force for the development of organic solar cells (OSCs). In this work, a new acceptor, BOEH‑4Cl, was designed based on the end-group chlorination of L8-BO. Theoretical calculations successfully predicted the expected experimental results based on the optoelectronic properties of BOEH-4Cl and L8-BO and intermolecular interaction of PM6/BOEH-4Cl or L8-BO.… Read More

The tuning of vertical morphology is critical and challenging for organic solar cells (OSCs). In this work, a high open-circuit voltage (VOC) binary D18-Cl/L8-BO system is attained while maintaining the high short-circuit current (JSC) and fill factor (FF) by employing 1,4-diiodobenzene (DIB), a volatile solid additive. It is suggested that DIB can act as a linker between donor or/and acceptor molecules, which significantly modifies the active layer morphology.… Read More

Cesium lead based all-inorganic perovskite solar cells (PSCs) are promising candidates for tandem solar cells owing to their favorable thermal stability and suitable bandgap. However, to exploit the advantage to the full, there is still huge room to reduce energy loss and enhance the V_OC. In this work, low-temperature processed ZnO was developed as an ETL alternative.… Read More